The main raw materials for producing para-aramid fiber such as Aramid 1414 include p-phenylenediamine (PDA) and terephthaloyl chloride (TPC), as well as auxiliary solvents and additives. The following raw materials are commonly used in the production of para-aramids and their functions:
- Core raw materials
(1) Para-phenylenediamine (PDA, Para-Phenylenediamine)
Function: Source of amine groups in the molecular chain of aramids.
Properties:
White to light yellow solid crystal.
Easily oxidized and darkens in air.
Provides rigidity and strength in the aramid molecular structure.
Source: p-Phenylenediamine is produced by chemical synthesis, usually from petrochemical feedstocks such as aniline.
(2) Terephthaloyl Chloride (TPC)
Role: Source of acyl groups in the molecular chain of aramids.
Properties:
White to light yellow crystal with irritating odor.
In the production of aramid, it participates in the polycondensation reaction as a dichloroyl chloride monomer.
Source: Obtained by chlorination reaction of terephthalic acid (PTA). - Solvent
(1) N,N-dimethylacetamide (DMAc, Dimethylacetamide)
Role: Dissolve reactants and provide a medium for polymerization reaction.
Properties:
Polar solvent, can stabilize the dispersion of polymer chain.
High recovery rate, good environmental protection.
Application: Commonly used in solution polymerization process of aramid.
(2) N-methyl pyrrolidone (NMP, N-Methyl-2-pyrrolidone)
Role: Similar to DMAc, used as solvent.
Properties:
Strong polarity, high temperature resistance.
Toxic, need to pay attention to the safety of operation.
Application: Used as a solvent substitute in some processes. - Catalyst
Use: Accelerate the reaction rate, improve the polymerization efficiency.
Common catalysts:
Boron trifluoride (BF₃) and its complexes.
Organic acid (such as formic acid, trifluoroacetic acid). - Additives
Antioxidant: Protect raw materials and products from oxidizing effects during the production process.
Stabilizer: Improve the stability of the system during polymerization reaction and spinning process.
Antistatic agent: reduce the generation of static electricity in spinning and subsequent processing. - Other auxiliary materials
(1) Neutralizer
Usage: used to neutralize the residual chloride or acid in the post-treatment stage of the reaction.
Commonly used neutralizing agents:
Ammonia (NH₃-H₂O).
Sodium carbonate (Na₂CO₃).
(2) Detergent
Purpose: To remove reaction by-products such as salts and unreacted monomers.
Commonly used detergents:
Deionized water.
Organic solvents (e.g., ethanol, acetone).
Treatment of by-products
By-product salts (e.g. HCl gas or chloride salts dissolved in solvents) are generated during the production process. These by-products need to be treated by appropriate processes (e.g. neutralization, recycling) to reduce environmental pollution.
Key raw materials in a simplified process
PDA + TPC → short-chain molecule.
Solvent → promotes the formation of a solution of long-chain molecules.
Catalysts and additives → control reaction rate and system stability.
Raw material sources and cost considerations
Core raw materials (PDA and TPC): usually chemical derivatives from the petrochemical industry.
Solvents and additives: recyclable types are selected according to environmental regulations.
The production cost of para-aramid is mainly determined by the core raw materials (PDA and TPC), whose purity and stability in the supply chain have a direct impact on the performance and final price of the product.