What are the raw materials for the production of para-aramids?

The main raw materials for producing para-aramid fiber such as Aramid 1414 include p-phenylenediamine (PDA) and terephthaloyl chloride (TPC), as well as auxiliary solvents and additives. The following raw materials are commonly used in the production of para-aramids and their functions:

  1. Core raw materials
    (1) Para-phenylenediamine (PDA, Para-Phenylenediamine)
    Function: Source of amine groups in the molecular chain of aramids.
    Properties:
    White to light yellow solid crystal.
    Easily oxidized and darkens in air.
    Provides rigidity and strength in the aramid molecular structure.
    Source: p-Phenylenediamine is produced by chemical synthesis, usually from petrochemical feedstocks such as aniline.
    (2) Terephthaloyl Chloride (TPC)
    Role: Source of acyl groups in the molecular chain of aramids.
    Properties:
    White to light yellow crystal with irritating odor.
    In the production of aramid, it participates in the polycondensation reaction as a dichloroyl chloride monomer.
    Source: Obtained by chlorination reaction of terephthalic acid (PTA).
  2. Solvent
    (1) N,N-dimethylacetamide (DMAc, Dimethylacetamide)
    Role: Dissolve reactants and provide a medium for polymerization reaction.
    Properties:
    Polar solvent, can stabilize the dispersion of polymer chain.
    High recovery rate, good environmental protection.
    Application: Commonly used in solution polymerization process of aramid.
    (2) N-methyl pyrrolidone (NMP, N-Methyl-2-pyrrolidone)
    Role: Similar to DMAc, used as solvent.
    Properties:
    Strong polarity, high temperature resistance.
    Toxic, need to pay attention to the safety of operation.
    Application: Used as a solvent substitute in some processes.
  3. Catalyst
    Use: Accelerate the reaction rate, improve the polymerization efficiency.
    Common catalysts:
    Boron trifluoride (BF₃) and its complexes.
    Organic acid (such as formic acid, trifluoroacetic acid).
  4. Additives
    Antioxidant: Protect raw materials and products from oxidizing effects during the production process.
    Stabilizer: Improve the stability of the system during polymerization reaction and spinning process.
    Antistatic agent: reduce the generation of static electricity in spinning and subsequent processing.
  5. Other auxiliary materials
    (1) Neutralizer
    Usage: used to neutralize the residual chloride or acid in the post-treatment stage of the reaction.
    Commonly used neutralizing agents:
    Ammonia (NH₃-H₂O).
    Sodium carbonate (Na₂CO₃).
    (2) Detergent
    Purpose: To remove reaction by-products such as salts and unreacted monomers.
    Commonly used detergents:
    Deionized water.
    Organic solvents (e.g., ethanol, acetone).
    Treatment of by-products
    By-product salts (e.g. HCl gas or chloride salts dissolved in solvents) are generated during the production process. These by-products need to be treated by appropriate processes (e.g. neutralization, recycling) to reduce environmental pollution.
    Key raw materials in a simplified process
    PDA + TPC → short-chain molecule.
    Solvent → promotes the formation of a solution of long-chain molecules.
    Catalysts and additives → control reaction rate and system stability.
    Raw material sources and cost considerations
    Core raw materials (PDA and TPC): usually chemical derivatives from the petrochemical industry.
    Solvents and additives: recyclable types are selected according to environmental regulations.
    The production cost of para-aramid is mainly determined by the core raw materials (PDA and TPC), whose purity and stability in the supply chain have a direct impact on the performance and final price of the product.

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